Raf Simons’ magic at the helm of Christian Dior Couture made its first outing thanks to Marion Cotillard, who donned a stunning ensemble from the designer’s debut Couture collection for the fashion house, for the London premiere of The Dark Knight Rises, last month.

More recently, Jessica Biel followed suit and stunned in an ultra-feminine powder pink Dior Couture dress at the Total Recall LA premiere, earlier this week.

But is was Rachel Weisz in a stunning, black strapless bustier Dior Couture Fall 2012 dress at the New York premiere for The Bourne Legacy earlier this week that had us picking up our dropped jaws from the table! Mrs Daniel Craig looked resplendent in a genius take on the perennially sexy Black Dress (although we’re going to call it the MBD or Mid Black Dress).

Completing her look was a black Charlotte Olympia ‘Pandora Domino’ clutch, Christian Louboutin ‘Bow Bow’ sandals, an elegant up do and a seductively scarlet pout.

We really can’t think of a more deserving (and painfully stylish) candidate for this week’s BDOTW!